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Study the relation between rheological, thermal and mechanical properties of waste polypropylene filled silica nanoparticles

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 نزار جواد هادي الاعرجي
20/12/2015 09:14:30
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Abstract:-
This paper investigates the rheological, thermal and mechanical properties of waste polypropylene (WPP) reinforced with silica (SiO2) nanoparticles (NPs). Recently the researches prove that the addition of NPs to the thermoplastic polymer produces significant change in its properties. SiO2 NPs of 0.001, 0.003, 0.006, 0.009, 0.012 and 0.015wt% were mixed with the WPP using twin screw extruder. The mixing process performed at 10 rpm and 190°C. The crystallinity of nanocomposite was examined by X-ray diffraction. The melt flow rate (MFR) and melt volume rate (MVR)are tested due to SiO2 NPs concentration at standard condition using melt flow index device also solid and melt density are examined. Differential Scanning Calomitry (DSC) is used to show the effect of SiO2 NPs concentration on the thermal history of nanocomposite. Charpy impact strength and hardness are tested. The results show that the crystallinity level and the crystallinity temperature decreases with SiO2 NPs concentration increasing while impact and hardness increasing. The MFR and MVR increases with NPs concentration increasing. Clear difference between solid and melt density is observed. There is a compatible between the thermal, rheological and mechanical properties.


  • وصف الــ Tags لهذا الموضوع
  • waste PP, SiO2 NPs, twin screw extruder, rheological, thermal and mechanical properties.