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الكلية كلية العلوم
القسم قسم الكيمياء
المرحلة 1
أستاذ المادة فؤاد حمزة عبد الشريفي
11/11/2016 07:08:39
Dihedral group Definition : For n?3 the Dihedral group is : D_n={s^j r^i } such that j ? {0,1} and i ? {0,1,2,?,n-1} Geometrically it s the group of symmetry of regular n-polygon consisting a clock wise rotations about the origin with angle (r^i ) i ? {0,1,2,?,n-1} and reflections about the principal axes (a cross lines through the origin (sr^i ) ) Example ( 1 ) D_3={1,r,r^2,s,sr,sr^2 } 1 is an identity element :(1) r is a clock wise rotations about the center with angle :(1? 2? 3) r^2 is a clock wise rotations about the center with angle :(1? 3?2) s is a reflection about the line L_1 : ( 2?3) sr is a reflection about the line L_2 :(1?3) sr^2 is a reflection about the line L_3 :(1?2)
Note : By the same way we can study the molecular vibration of CH_3 Example ( 2 ) : Describe the molecular vibration of Methane CH_4 We may be study D_4={1,r,r^2,r^3 ,s,sr,sr^2,sr^3 } 1 is an identity element which make all H constant :(1) r is a clock wise rotations about the center with angle :(1?2? 3?4) r^2 is a clock wise rotations about the center with angle ??(1?? 3) (2??4) r^3 is a clock wise rotations about the center with angle :(1?4?3?2) s is a reflection about the line L_1 ?(2?4 ) sr is a reflection about the line L_2 ?(1?2)(3?4) sr^2 is a reflection about the line L_3 ?(1?3 ) sr^3 is a reflection about the line L_4 ?(1?4)(2?3) Example ( 3 ) : Discuss the molecular vibration of Arsenic pentachloride AsCl_5 We may be study D_5={1,r,r^2,r^3,r^4 ,s,sr,sr^2,sr^3,sr^4 } 1 is an identity element which make all Cl constant r is a clock wise rotations about the center with angle :(1?2? 3?4?5) r^2 is a clock wise rotations about the center with angle :(1?3? 5?2?4) r^3 is a clock wise rotations about the center with angle :(1?4? 2?5?3) r^4 is a clock wise rotations about the center with angle :(1?5?4?3?2) s is a reflection about line L_1 ?(2?5)(3?4) sr is a reflection about line L_2 ?(1?2)(3?5) sr^2 is a reflection about line L_3 ?(1?3)(4?5) sr^3 is a reflection about line L_4 ?(1?4)(2?3) sr^4 is a reflection about line L_5 ?(1?5)(2?4) Question: Discuss the molecular vibration of Benzene H_6 C_6.
المادة المعروضة اعلاه هي مدخل الى المحاضرة المرفوعة بواسطة استاذ(ة) المادة . وقد تبدو لك غير متكاملة . حيث يضع استاذ المادة في بعض الاحيان فقط الجزء الاول من المحاضرة من اجل الاطلاع على ما ستقوم بتحميله لاحقا . في نظام التعليم الالكتروني نوفر هذه الخدمة لكي نبقيك على اطلاع حول محتوى الملف الذي ستقوم بتحميله .
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