(Fourier transform mechanical spectroscopy (FTMS )
The evolution of visco-elastic properties in non-Newtonian fluids exhibiting time-dependent rheological changes is a matter of wide scientific interest, particularly so in systems undergoing gelation. The gel-point, where a threedimensional network structure is established, may be identified rheologically by the establishment of a characteristic frequency dependence of the dynamic moduli, and an associated frequency independent loss tangent [Winter and . [Chambon, 1986 This criterion for gel-point detection, and the non-equilibrium nature of systems undergoing gelation, requires that data be obtained rapidly over a wide range of frequency, prompting the development of a frequency multi-plexing technique known as Fourier Transform Mechanical Spectroscopy, FTMS, at several frequencies simultane-ously,which allows the measurement of G . [rather than consecutively, as in a conventional test [Holly et al., 1988 The technique, initially developed to measure visco-elastic properties in the curing of polymers [Malkin et al., 1984], has been applied to gels (In and Prud’homme, 1993) and model visco-elastic fluids [Davies and Jones, 1994]. In a variation of the technique, dynamic mechanical properties are determined using the Fourier transform of pulsed deformations [Vratsanos and Farris, .[1988
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